Lithium perchlorate

Lithium perchlorate

Perchloric acid lithium salt

CAS 7791-03-9

Chemical Formula LiClO4

Molecular Weight 106.39 g/mol

Lithium perchlorate (LiClO4) is a white, crystalline salt that is highly soluble in water and many organic solvents. It's known for its strong oxidizing properties and is used in various applications, including as an electrolytic salt in batteries and in chemical oxygen generators. Lithium perchlorate can be produced through several methods, including the reaction of sodium perchlorate with lithium chloride or lithium carbonate.  

Industrial Uses

1. Performance Chemicals

  • Activation of carbonyl and other oxygen-containing compounds: Lithium perchlorate can activate carbonyl groups and other oxygen-containing compounds, facilitating various reactions. 
  • Ring opening of epoxides: It catalyzes the ring opening of epoxides with amines, leading to β-aminoalcohols. 
  • Acylation: It can catalyze the acylation of hindered alcohols and phenols under solvent-free conditions. 
  • Conjugate addition: It promotes the 1,4-conjugate addition of O-silylated ketene acetals to hindered α,β-unsaturated carbonyl systems. 
  • Baylis-Hillman reaction: It acts as a co-catalyst in the Baylis-Hillman reaction, which involves the coupling of α,β-unsaturated carbonyls with aldehydes. 
  • Cyanosilylation: Solid Lithium perchlorate acts as a mild Lewis acid for promoting cyanosilylation of carbonyl compounds under neutral conditions.
  • Synthesis of α-aminophosphonates: It facilitates the synthesis of α-aminophosphonates under solvent-free conditions.

2. Energy

  • Electrolyte: Lithium perchlorate is a common electrolyte salt in lithium-ion batteries, especially in the early stages of their development. 
  • Solid Electrolytes: It's also used as a component in solid polymer electrolytes, often combined with polyethylene oxide and ceramic nanoparticles.

Specifications

Assay 95%
Appearance White crystalline solid or powder
Odor Odorless
Boiling Point Decomposes before boiling
Melting Point 236°C
Density 2.43 g/cm3
Solubility Very soluble in water, methanol, ethanol, acetone, ethyl acetate, and acetonitrile
Viscosity Not applicable
Flash Point Not flammable

Hazard Symbols

Acute Toxicity
Irritants/Sensitisers/Other Hazards

FAQs

1. What is the current price of Lithium perchlorate in India?
The price of Lithium perchlorate can vary based on factors such as purity, quantity, etc. For the most accurate and competitive pricing, please contact us at +91.6301 00 6301 directly for a customized quote tailored to your needs.

2. Where can I buy Lithium perchlorate in India?
You can purchase Lithium perchlorate from MULTICHEM, a leading exporter with a reputation for quality and reliability. We provide convenient options for bulk orders and direct shipments across global markets. For more details on how to place an order, please visit our website or contact our sales team.

3. What is the minimum order quantity (MOQ) for Lithium perchlorate? 
Our minimum order quantity (MOQ) for Lithium perchlorate is designed to cater to both small-scale and large-scale needs. The MOQ depends on the packing size of the product which could range from 25 kg to 250kg.

4. How can I ensure the quality of Lithium perchlorate supplied by Multichem?
We adhere to stringent quality control processes to ensure that our products meet the highest standards of purity and effectiveness. They undergo rigorous testing and quality checks to guarantee that they comply with industry specifications. We provide a Certificate of Analysis (CoA) with every shipment to ensure transparency and quality assurance.