Bismuth chloride

Bismuth chloride

Bismuth(III) chloride; bismuth trichloride; butter of bismuth

CAS 7787-60-2

Chemical Formula BiCl₃

Molecular Weight 315.34 g/mol

Bismuth chloride, also known as bismuth trichloride (BiCl3), is an inorganic compound and a source of the Bi3+ ion. It's a covalent compound with a pyramidal molecular structure in the gas phase and crystal. Bismuth chloride acts as a catalyst in various organic reactions, such as the Mukaiyama aldol and Michael reactions. When it reacts with water, it undergoes hydrolysis, forming bismuth oxychloride and hydrochloric acid. 

Industrial Uses

1. Performance Chemicals

  • Catalysis: Bismuth chloride acts as a catalyst in reactions like Friedel-Crafts acylation and alkylation, which are fundamental in organic synthesis.  
  • Organic Synthesis: It's involved in the synthesis of other bismuth compounds and is used in reactions like the allylation of secondary benzyl alcohols and the preparation of thiiranes from oxiranes. 
  • Multicomponent Reactions: Bismuth chloride can catalyze multicomponent reactions, such as the synthesis of hexahydroimidazo[1, 2-a]pyridines, offering a potentially greener approach due to the non-toxicity of bismuth compounds and the avoidance of complex purification steps. 
  • Thioenol Ether Synthesis: Bismuth chloride can catalyze the synthesis of thioenol ethers from 1,3-dicarbonyls/2-oxindoles under ultrasonic irradiation.

2. Pharmaceuticals

  • Catalyst in Synthesis: Bismuth(III) chloride acts as a Lewis acid catalyst in various organic reactions. This catalytic activity is important in the synthesis of other bismuth compounds, some of which have pharmaceutical applications.

3. Polymers & Resins

  • Catalyst in Polymer Reactions: Bismuth chloride acts as a Lewis acid catalyst, meaning it can accept an electron pair to facilitate various chemical reactions involving polymers. Examples include acetolysis, hydrolysis, and alcoholysis, which are crucial in modifying polymer structures and properties.
  • Flame Retardancy: Bismuth compounds, including Bismuth chloride, can enhance the flame retardancy of polymers when combined with other flame retardants like chloroparaffins. The flame retardant effect is not solely attributed to the formation of Bismuth chloride or bismuth oxychloride (BiOCl) when heated, but rather requires their presence alongside the chloroparaffin. This synergistic effect can significantly improve the fire safety of polymers, such as polypropylene.

4. Metal Treatment

  • Alloy Creation:  Bismuth chloride is a key ingredient in the production of bismuth-based alloys, which are used in specialized industrial components. These alloys often have unique properties, such as low melting points, making them useful in applications like fire detectors, electric fuses, and solders. 
  • Catalysis: Bismuth chloride acts as a catalyst in various chemical reactions, including acetolysis, hydrolysis, and alcoholysis, which are relevant in metal processing. Catalysts enhance reaction rates and improve the efficiency of metal treatment processes.

Specifications

Assay 98%
Appearance White to pale yellow crystalline solid
Odor Odorless
Boiling Point 447°C
Melting Point 227°C
Density 4.75 g/cm3
Solubility Reacts with water; soluble in hydrochloric acid and alcohol
Viscosity Not applicable
Flash Point Not flammable

Hazard Symbols

Irritants/Sensitisers/Other Hazards

FAQs

1. What is the current price of Bismuth chloride in India?
The price of Bismuth chloride can vary based on factors such as purity, quantity, etc. For the most accurate and competitive pricing, please contact us at +91.6301 00 6301 directly for a customized quote tailored to your needs.

2. Where can I buy Bismuth chloride in India?
You can purchase Bismuth chloride from MULTICHEM, a leading exporter with a reputation for quality and reliability. We provide convenient options for bulk orders and direct shipments across global markets. For more details on how to place an order, please visit our website or contact our sales team.

3. What is the minimum order quantity (MOQ) for Bismuth chloride? 
Our minimum order quantity (MOQ) for Bismuth chloride is designed to cater to both small-scale and large-scale needs. The MOQ depends on the packing size of the product which could range from 25 kg to 250kg.

4. How can I ensure the quality of Bismuth chloride supplied by Multichem?
We adhere to stringent quality control processes to ensure that our products meet the highest standards of purity and effectiveness. They undergo rigorous testing and quality checks to guarantee that they comply with industry specifications. We provide a Certificate of Analysis (CoA) with every shipment to ensure transparency and quality assurance.